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Q.

Every Homologous series is characterised by certain type of reactions. Identify the correct match 

 

Column - I

(Homologous series)

 

Column - II

(Type of reaction)

I)Alkenesa)Nucleophilic substitution
II)Aromatic Hydrocarbonsb)Electrophilic addition
III)Halo alkanesc)Nucleophilic addition
IV)Carbonyl compoundsd)Electrophilic substitution
 IIIIIIIV
1)dbca
2)cdba
3)badc
4)bdac

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a

1

b

2

c

3

d

4

answer is D.

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Detailed Solution

 

Column - I

(Homologous series)

 

Column - II

(Type of reaction)

I)Alkenesb)Electrophilic addition
II)Aromatic Hydrocarbonsd)Electrophilic substitution
III)Halo alkanesa)Nucleophilic substitution
IV)Carbonyl compoundsc)Nucleophilic addition

In alkanes, double bonded carbon is sp2 hybridized. They are electron rich specie and can undergo electrophilic addition reaction. In aromatic hydrocarbons, electrophilic substitution reaction is possible because if it undergoes electrophilic addition reaction, then its aromaticity is destroyed.

In haloalkanes, there is a partial positive charge on C atom (attached to the halogen) and nucleophilic easily attacks on the C and replaces the halogen. Therefore, haloalkanes undergoes nucleophilic substitution reaction.

In carbonyl compounds, carbonyl carbon atom is electron-deficient and hence, undergoes nucleophilic addition reaction.

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