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Q.

Examples of electron withdrawing groups relative to hydrogen are

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a

-NO2

b

-COOR

c

All of these

d

-COOH

answer is D.

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Detailed Solution

Based on the ability of a substituent to withdraw or donate electron density, the substituents can be classified as electron-withdrawing or electron donating groups relative to hydrogen. Halogens and many other group such as nitro -NO2, cyano (-CN), carboxy (-COOH),

ester (-COOR), aryloxy -OAr, e.g. -OC6H5, etc.,  are electron-withdrawing groups. On the other hand, the alkyl groups like methyl -CH3 and ethyl -CH2-CH3 are usually considered as electron donating groups.

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Examples of electron withdrawing groups relative to hydrogen are