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Q.

Excess of KI reacts with CuSO4 solution and then Na2S2O3 solution is added to it. Which of the statements is incorrect for this reaction?

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a

Evolved I2 is reduced

b

Cu2I2 is formed

c

CuI2 is formed

d

Na2S2O3 is oxidised

answer is B.

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Detailed Solution

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2Cu+2SO4+4KI-1Cu2I2+I20+2K2SO4

Thus, CuI2​ is not formed in this reaction.

The liberated iodine is titrated with sodium thiosulphate to form sodium tetrathionate.

2Na2S+22O3+I2Na2S2.54O6+2NaI  

Iodine is reduced and sodium thiosulphate  is oxidized.

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