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Q.

Excess of Kl reacts with CuSO4 solution and then Na2S2O3 solution is added to it. Which of the statements is incorrect for this reaction?

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a

Na2S2O3 is oxidised

b

Cul2 is formed

c

CO2 +O2 is formed

d

Evolved I2 is formed

answer is B.

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Detailed Solution

Copper sulphate reacts with potassium iodide to form cuprous iodide and iodine.
2CuSO4​+4KI→Cu2​I2​↓+I2​+2K2​SO4​
Thus, CuI2 is not formed in this reaction.
Hence, the option B is incorrect and option A is correct.
The liberated iodine is titrated with sodium thiosulphate to form sodium tetrathionate.
2Na2​S​2O3​+I2​→Na2​S4​O6​+2NaI
Iodine is reduced and sodium thiosulphate  is oxidized.

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