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Q.

Experiment

[A]

Mole/lit

[B]

Mole/lit

Rate of reaction

Mole lit1min1

I0.20.21.2×102
II0.60.41.44×101
III0.60.85.76×101
IV0.80.24.8×102

The above data is recorded for  A+BAB, the correct rate law equation is

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a

KA2B

b

KA2B2

c

KAB

d

K A B2

answer is A.

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Detailed Solution

consider Experiment II & III

[A] is constant

 [B] is doubled and rate increased by a factor of four

rate  =  KCn Cnrate

     Order w.r.t B

2x=4 2x=22 X = 2

Consider experiment I & IV

[B] is constant

[A] is quadrapled and rate  increased by factor of four

 Order w.r.t A

4y=4 Y = 1 

Rate = K A B2

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