Q.

Explain reversible and irreversible processes. Describe the working of carnot engine. Obtain an expression for the efficiency?

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Detailed Solution

Reversible process : A process that can be retraced back in the opposite direction in such a way that the system passes through the same states as in the direct process and finally the system and surroundings return to their original states is called a reversible process.
Examples :
1) Peltier effect and seebeck effect
2) Fusion of ice and vaporization of water
Irreversible process : A process that cannot be retraced back in the opposite direction is called as irreversible process.
Examples : 1) Work done against friction
2) Diffusion of gases
3) Joule heating
Carnot engine: A reversible heat engine operating between two temperatures is called a carnot engine. The cycle operating it is known as carnot cycle. Carnot cycle contains the following four steps

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1) In isothermal expansion from A to B
 Work done W1=Q1=RT1logV2V1
2) In adiabatic expansion from B to C
 Work done W2=RT1T2γ1 ...(2)
3) In isothermal compression from C to D
Workdone W3
=Q2=RT2logV4V3=RT2logV3V4. ...(3)
4) In adiabatic compression from D to A
W4=RT2T1γ1=RT1T2γ1 ...(4)
* In adiabatic expansion from B to C
T1V2γ1=T2V3γ1 ...(5)
* In adiabatic compression from D to A
T1V1γ1=T2V4γ1   ...(6)56V2V1γ1=V3V4γ1V2V1=V3V4  ...(7)
From (3) & (7)
W3=RT2logV3V4=RT2logV2V1
Total workdone (W)=W1+W2+W3+W4
W=RT1T2logV2V1
Efficiency(η)=WQ1=RT1T2logeV2V1RT1logeV2V1
η=T1T2T1η=1T2T1

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