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Q.

Explain the following reactions
a) Sand meyer reaction
b) Gattermann’s reaction

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Detailed Solution

a) Sandmeyer’s reaction:
The nucleophiles like Cl, Br, CN, are introduced in the benzene ring when bezene diazonium halide reacts with HCl, HBr & KCN in the presence of cuprous ion.
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b) Gatterman Reaction: Cl and Br are introduced in the benzene ring when benzene diazonium chloride reacts with HCl (or) HBr in the presence of copper powder
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