Q.

Explain the optical isomerism in octahedral complexes.

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Detailed Solution

Optical isomers are the stereoisomers that are nonsuperimposable mirror images of each other and they differ in the direction in which they rotate plane-polarised light.They do not possess the plane of symmetry. The molecules which are non super-imposable mirror image of each other are called chiral and this property is called chirality. The d and l isomers are called enantiomers. Optical isomerism is common in octahedral complexes involving 1, 2, 3 symmetrical didentate ligands. e.g [Co(Cl)2(en)2]+

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It contains three symmetrical didentate ligands, e.g., [Co(en)3​]3+. They have dextro and laevo forms.

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