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Q.

Explain the structure of diborane ?

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Detailed Solution

I) Structure of diborane
i) Diborane is an electron deficient molecule. It contains 12 electrons and short of 2 electrons or the formation of covalent bond.
ii) Electron diffraction studies have shown that diborane contains two co-planar BH2 groups. And has two types of hydrogen atoms.
i) Four terminal H-atoms (Ht)
ii) Two Bridge H-atoms (Hb)
Question Image
II) Orbital structure of diborane
i) In B2H6 each boran atom undergoes sp3 hybridisation.
ii) out of the four hybrid orbitals of boran atom, three orbitals have one electron each and fourth orbital is vacant.
iii) In forming B –H – B Bridge, sp3 hybrid orbital with one electron from one boran atom, 1sorbital of one bridge hydrogen and the vacant sp3 hybrid orbital of the second boran atom
overlaps as shown in the figure.
Question Image
iv) The B-H-B bridges present in Diborane are abnormal bonds.
v) They are considered as three centered two electron bonds. This type of bond is called banana bond or tau bond. In this type of bond pair of electrons hold three atoms.

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