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Q.

FeCl2X;  FeHClY.

X and Y are metal chlorides. Regarding X and Y, choose the incorrect statement is

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a

In aqueous medium both X and Y exhibit paramagnetism

b

The pair of X and Y illustrate law of multiple proportions

c

X on oxidation gives Y

d

Equivalent weight of metal in ‘X’ and Y is different

answer is C.

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Detailed Solution

FeCl2FeCl3Fe+3

FeHClFeCl2Fe+2

Fe3+ is already in maximum oxidation state, hence it cannot further lose electrons.

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Fe→Cl2X;  Fe→HClY.X and Y are metal chlorides. Regarding X and Y, choose the incorrect statement is