Q.

Fe2O3(g)+3CO(g)2Fe(s)+3CO2(g);  ΔH=26.8kJ
FeO(g)+CO(g)Fe(s)+CO2(g);  ΔH=16.5kJ
From the above data, 
The value of ΔH for the following reaction Fe2O3(g)+CO(g)2FeO(s)+CO2(g) is

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a

+ 10.3 kJ

b

 – 10.3 kJ

c

+ 6.2 kJ

d

– 43.3 kJ

answer is D.

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Detailed Solution

Fe2O3(g)+3CO(g)2Fe(s)+3CO2(g)
ΔH=26.8kJ.......(i)
FeO(s)+CO(g)Fe(s)+CO2(g)
ΔH=16.5kJ.....(ii)
Fe2O3(g)+CO(g)2FeO(g)+CO2(g)
ΔH=?.....(iii)
Eq. (iii) can be obtained as : 
(i)-  2(ii) = -26.8 – 2(-16.5) = - 26.8 + 33.0 = + 6.2 kJ

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Fe2O3(g)+3CO(g)→2Fe(s)+3CO2(g) ;  ΔH=−26.8kJFeO(g)+CO(g)→Fe(s)+CO2(g) ;  ΔH=−16.5kJFrom the above data, The value of ΔH for the following reaction Fe2O3(g)+CO(g)→2FeO(s)+CO2(g) is