Q.

    Fe3+aqYellow+SCNaqFeSCN2+Redaq
To the equilibrium mixture,  HgCl2A and  KSCNB are added in two separate experiments.  Red colour intensity decreases by the addition of 

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a

B only 

b

Both A and B 

c

Neither A nor B 

d

A only 

answer is C.

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Detailed Solution

HgCl2    will remove SCNΘ by forming complex while KSCN will increase SCNΘ when added in solution.  Red colour intensity will decreases by addition of HgCl2 as equilibrium will shift in backward direction due to removal of reaction.

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