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Q.

FeCl3 on reaction with K4[Fe(CN)6] in aq solution gives blue colour and these are separated by a semi permeable membrane Due to osmosis there is

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a

blue colour formation in the solution of FeCl3

b

blue colour formation in the solution of K4[Fe(CN)6]

c

no blue colour formation

d

blue colour formation in both the solutions

answer is D.

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Detailed Solution

Osmotic pressure ,π=iCRT

For FeCl3​ solution, i=4, therefore i×C=4×(0.1) 

For K4​[Fe(CN)6​], i=5 , and i×C=5×(0.01)

Since, i×C is more for FeCl3​ solution and we know that in osmosis, flow of solvent takes place from dilute to a concentrated solution.

So, the blue colour formation will not take place.

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