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Q.

Find IUPAC name of the hydrate isomer of CrCl36H2O, which is having lowest electrical conductivity.

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a

Hexaaquachromium(Ill)chloride

b

Pentaaquachloridochromium(Ill) chloridemonohydrate

c

Triaquatrichloridochromium(Ill)trihydrate

d

Tetraaquadichloridochromium(Ill)chloridedihydrate

answer is B.

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Detailed Solution

CrH2O4Cl2Cl2H2O; hydrate isomer of complex CrH2O6Cl3 has lowest electrical conductivity, because it gives only two ions on ionisation in aqueous medium.

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