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Q.
Find out number of compounds which are more acidic than benzoic acid, from following
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answer is 4.
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Detailed Solution

4 compounds
Given Compounds:
- Formic Acid (HCOOH):
- Has no benzene ring and is simpler than benzoic acid. Its acidity is stronger because the absence of additional substituents minimizes steric and electronic effects.
- More acidic than benzoic acid.
- Oxalic Acid (H₂C₂O₄):
- A dicarboxylic acid. Its second carboxylic group enhances the electron-withdrawing effect, stabilizing the conjugate base.
- More acidic than benzoic acid.
- p-Toluic Acid (COOH with CH₃ group):
- The methyl group (CH₃) is an electron-donating group (EDG), which decreases the acidity of the molecule.
- Less acidic than benzoic acid.
- p-Nitrobenzoic Acid (COOH with NO₂ group):
- The nitro group (NO₂) is a strong electron-withdrawing group (EWG), significantly increasing acidity by stabilizing the conjugate base.
- More acidic than benzoic acid.
- p-Dimethylaminobenzoic Acid (COOH with N(CH₃)₂ group):
- The dimethylamino group (N(CH₃)₂) is a strong electron-donating group (EDG), which decreases acidity by destabilizing the conjugate base.
- Less acidic than benzoic acid.
- p-Trifluoromethylbenzoic Acid (COOH with CF₃ group):
- The trifluoromethyl group (CF₃) is a strong electron-withdrawing group (EWG), significantly increasing acidity by stabilizing the conjugate base.
- More acidic than benzoic acid.
Compounds more acidic than benzoic acid are:
- Formic Acid
- Oxalic Acid
- p-Nitrobenzoic Acid
- p-Trifluoromethylbenzoic Acid
4 compounds are more acidic than benzoic acid.
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