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Q.

Find out total number of paramagnetic complexes which are inner orbital complexes:
[Cr(NH3)6]Cl3,[Co(NH3)6](NO3)2,[Ni(NH3)6]SO4,K2[PtCl6],[V(H2O)6](SO4),  [Mn(NH3)6](SO4)  ,  [Fe(H2O)5(NO)]SO4,K3[CuCl4],Na4[Fe(CN)5(NOS)] .
 

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answer is 3.

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Detailed Solution

[Cr(NH3)6]Cl3,[Ni(NH3)6]SO4  and  [Mn(NH3)6]SO4  are inner orbit complexes and are paramengetic.

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