Q.

Find the number of complexes following sidgwick EAN rule:

Ag(CN)2            Hg42

Ti(CO)62,                 TiσC5H52πC5H52]

Fe(CN)6NO2

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answer is 2.

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Detailed Solution

When the total number of electrons in the metal ion reaches the atomic number of the noble gas in that series, the metal ion in a coordination complex will stop absorbing electrons.

Ag(CN)2471+4=50HgI42802+8=86Ti(CO)6222+2+12=36TiσC5H52πC5H52224+4+12=34FeCN6NO2263+12=35

Here, complexes which follow sidgwick EAN rule are:

Hg42Ti(CO)62

Hence correct answer is 0002.

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