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Q.

Find the number of complexes which satisfy at least three of the following four conditions : (a) Primary valence • 3 (b) Secondary valence= 6 (c) Oxidation number of central atom > +3 (d) Number of ions per molecule> 3

I.  PtNH34PtCl6         II. CoNH36Cl3

III. CoNH35OH2Cl3      IV. PtNH36Cl4

V. KPtCl5NH3                    VI. CoCl2,(en)2+

VII. Ni(CO)4                            VIII.[Co(EDTA)]

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answer is 3.

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Detailed Solution

(II), (iii) and ([V) satisfy at least three given conditions.

Hence correct answer is 0003. 

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Find the number of complexes which satisfy at least three of the following four conditions : (a) Primary valence • 3 (b) Secondary valence= 6 (c) Oxidation number of central atom > +3 (d) Number of ions per molecule> 3I.  PtNH34PtCl6         II. CoNH36Cl3III. CoNH35OH2Cl3      IV. PtNH36Cl4V. KPtCl5NH3                    VI. CoCl2,(en)2+, VII. Ni(CO)4                            VIII.[Co(EDTA)]−