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Q.

Find the number of reactions where CaCl2 is the product from the following :

(i)Ca(OCl)Cl+FeSO4+H2SO4

(ii)Ca(OCl)Cl+H2SO4

(iii)Ca(OCl)Cl+CaCO3

(iv)Ca(OCl)Cl+Na3AsO4

(v) Ca(OCl)Cl+NH3

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answer is 3.

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Detailed Solution

Out of the given five reactions, three of them lead to the formation of calcium chloride.

 (i) Ca(OCl)Cl+2FeSO4+H2SO4Fe2SO43+CaCl2+H2O

The reaction of bleaching powder with Iron(ii) sulphate and Sulphuric acid gives Calcium chloride, Iron (III)sulphate and water.

 (iv) Ca(OCl)Cl+Na2AsO3CaCl2+Na3AsO4

Calcium chloride along with sodium arsenate is formed when Sodium arsenite reacts with bleaching powder as shown above.

 (v) Ca(OCl)Cl+2NH3CaCl2+3H2O+N2

Bleaching powder in reaction with ammonia gives calcium chloride, nitrogen gas, and water as products.

 3 of the given reaction gives CaCl2 as the product.

Therefore the correct answer is 3.

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