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Find the pair of compounds in which both show geometrical as well as optical isomerism :

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$M (AA)_{3} and M (AB)_{3}$

$[M (AA)_{2} a_{2}] and [M (AA) ab]$

$[Zn (gly)_{2}] and {[{NiCl}_{4}]}^{2 -}$

None of these

answer is D.

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Detailed Solution

Unlike optical isomers, which are pairs of compounds that are mirror images of one another, geometric isomers are pairs of compounds with the same substituents attached to a carbon-carbon double bond in a unique way.

Geometric isomerism and opticaly is absent in the tetrahedral compounds of types ${MA}_{4}$ ${MA}_{4} B$ ,, ${MA}_{2} B_{2}$ , and ${MA}_{2} BC$ .

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