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Q.

Find the value of wave number (ν) in terms of Rydberg’s constant, when transition of electron takes place between two levels of He+ ion whose sum is ‘4’ and difference is ‘2’.

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a

32RH/9

b

8RH/9

c

3RH/4

d

5RH/4

answer is B.

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Detailed Solution

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For He+, Z = 2;

Given n1 + n2 = 4.....(1)

n2 - n1 = 2.....(2)

Adding (1) and (2)

2n2 = 6

n2 = 3

3 - n1 = 2

n1 = 1

v¯=1λ=RH22112-132

=4RH89

  =32RH9           

 

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