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Q.

Fluorine has the highest electro negativity among the halogens on the Pauling scale, but the electron affinity of fluorine is less than that of chlorine because

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a

the atomic number of fluorine is less than that of chlorine

b

fluorine do not show positive oxidation state

c

chlorine can accommodate an electron better than fluorine by utilising its large atomic size and vaccant d orbitals

d

small size, high electron density favours  addition of an electron to fluorine than chlorine

answer is C.

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Detailed Solution

Due to empty d-orbital, screening effect decreases hence, tendency to attract electron increases.

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