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Q.

Following data has been given for CO2 for the concentration in H2O.

TemperatureHenry's constantPressure
273 K600 atm0.30 atm
333 K3400 atmp2

If solution of CO2 in H2O is heated from 273 to 333 K, pressure (p2) needed to keep CO2 in the solution is

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a

0.468 atm

b

0.108 atm

c

1.7 atm

d

0.212 atm 

answer is B.

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Detailed Solution

By Henry's law at 273 K,

χCO2 (mole fraction of CO2=pKH=0.30600

By Henry's law at 333 K, 

χCO2=pKH=p23400

p23400=0.30600

p2=0.30×3400600=1.7 atm

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