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Q.

Following data is given at  T = 298 K 

λ eq for Ba(OH)2=228.8ohm1cm2eq1

λ eq for BaC2=120.3ohm1cm2eq1

λ0 eq for NH4C=129.8ohm1cm2eq1

Specific conductance for 0.2N    NH4OH solution is4.766×10–4ohm–1cm–1

Then the value of pH of the given solution of NH4OH will be nearly.

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a

9.2

b

11.3

c

12.1

d

2.7

answer is B.

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Detailed Solution

λBa(OH)2=λBa+2+λOH

λBaCl2=λBa+2+λCl

λNH4Cl=λNH4+λCl

λNH4OH=λNH4+λOH=129.8+222.8120.3=238.3m

λ=K×1000C=4.766×104×10000.2

α==0.01OH=0.01×0.2=2×103POH3log2

pH = 11.3

 

 

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