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Q.

Following four solutions are prepared by mixing different volumes of NaOH and HCl of different concentrations, pH of which one of them will be equal to 1?

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a

55mLM10HCl+45mLM10NaOH

b

75mLM5HCl+25mLM5NaOH

c

100mLM10HCl+100mLM10NaOH

d

60mLM10HCl+40mLM10NaOH

answer is B.

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Detailed Solution

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75mLM5HCl+25mLM5NaOH 25mLM5NaOH will neutralise 25mLM5HCl

75-25=50mLM5HCl will remain. Total volume will be 75+25=100 mL When 50mLM5HCl is diluted to 100 mL, molarity will reduce to half, i.e., M10 H+=HCl=110 pH=-log10H+=-log10110=

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