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Q.

Following solutions were prepared by mixing different volumes of NaOH and  HCl of different concentrations.
A.  60mLM10HCl+40mLM10NaOH
B.  55mLM10HCl+45mLM10NaOH
C.  75mLM5HCl+25mLM5NaOH
D.  100mLM10HCl+100mLM10NaOH
The pH of which of them will be equal to 1?

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a

B

b

A

c

D

d

C

answer is D.

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Detailed Solution

pH=-log(NAVA-NBVBVA+VB)(M=N)
pH=-log(75×0.225×0.275+25)
pH=-log10(155100)
pH=-log10(10100)
pH=-log10101=1
(B) [H+]=55×110-45×11055+45
=5.5×4.5100=102
PH=2
(A) [H+]=60×110-40×11060+40
=2100=2×10-2
PH=2-log2=1.6990
(D) [H+]=100×110-100×110=0
Neutral solution PH=7

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