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Q.

Following statements regarding the periodic trends of chemical reactivity of the alkali metals and the halogens are given. Which of these statements gives the correct picture?

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a

Chemical reactivity increases with increase in atomic number down the group in both the alkali metals and halogens

b

In alkali metals the reactivity increases but in the halogens it decreases with increase in atomic number down the group

c

The reactivity decreases in the alkali metals but increases in the halogens with increase in atomic number down the group

d

In both the alkali metals and the halogens the chemical reactivity decreases with increase in atomic number down the group

answer is B.

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Detailed Solution

The alkali metals area highly reactive because their first ionization potential is very low and hence they have great tendency to loses electron from unipositive ion. On moving down group – I from Li to Cs ionization enthalpy decrease hence the reactivity increases. The halogens are most reactive elements due to their low bond dissociation energy, high electron affinity and high enthalpy of hydration of halide ion. However their enthalpy of hydration of halide ion. However their reactivity decrease in atomic number

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