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Q.

Following the transition elements and once crossing Zinc, (IE)1 drops abruptly in Ga, In or TI. This is due to

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a

increases in atomic radius leads to high attraction between the electron and nucleus.

b

None of the above is correct

c

decrease in atomic size

d

removal of an electron from the singly occupied np-orbitals of higher energy than the ns-orbitals of Zn, Cd and Hg.

answer is C.

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Detailed Solution

Ga(31)=[Ar]184s23d104p1 easier to remove Zn(30)=[Ar]184s23d10 difficult to remove 
Similar case of In /Cd and TI/ Hg.

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