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Q.

Following two equilibrium is simultaneously established in a container

PCl5(g)PCl3(g)+Cl2(g)CO(g)+Cl2(g)COCl2(g)

If some Ni(s) is introduced in the container forming Ni(CO)4(g) then at new equilibrium :

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a

PCl3 concentration will decrease

b

Cl2 concentration will remain same

c

CO concentration will remain same

d

PCl3 concentration will increase

answer is B.

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Detailed Solution

A reduction in product concentration favours the forward reaction. The rate of reverse reaction will reduce quickly, then gradually increase until equilibrium is restored. Simultaneously, the forward response rate will steadily decrease.

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