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Q.

For \large A\, + \,B\, \rightleftharpoons \,C + D, \large \Delta H\, = \, - QKJ, Kf and Kb respectively are 0.25 and 5000 at 400K. Now, Kc for same process at 500K may be

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a

 

5.2×10-5

b

 

4.5×10-4

c

 

5×10-5

d

4×10-5

 

answer is A.

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Detailed Solution

A + B C + D, ΔH = -QKJ

At 400 K Kf = 0.25; Kb = 5000

\large {K_{eq}} = \frac{{0.25}}{{5000}} = 5 \times {10^{ - 5}}

 

 

 

The reaction is exothermic at higher temperature, 500 K value of Keq will be lesser than\large 5 \times {10^{ - 5}}

By inspection option (1) is the only value which is lesser than\large 5 \times {10^{ - 5}}

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