Q.

For first order reaction, if rate constant at 17° is2.8×105s1 and at 27°C is2.8×104s1 . Then activation energy is

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a

160.1 KJ mol1

b

166.3 KJ mol1

c

180 KJ mol1

d

170KJ mol1

answer is B.

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Detailed Solution

The Arrhenius Equation is given below.

logk2k1=Ea2.303R[T2T1T1T2]

Put the given values in this equation to get the activation energy.

log[2.8×1042.8×105]=Ea2.303×8.314[12901300]

     Ea=2.303×8.314×290×300×log1010

          =166299.6 J mol1

 Ea=166.3 KJ mol1

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