Q.

For 1 molal aqueous solution of the following compounds, which one will show the highest freezing point?

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a

COH2O6Cl3

b

COH2O3Cl33H2O

c

COH2O5ClCl2·H2O

d

COH2O4Cl2Cl.2H2O

answer is C.

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Detailed Solution

ΔTf=i×m×Kfm=1 (given) ΔTF=i×Kf For ionic compounds, vant Hoff factors  are equal to the number of distinct  ions in the substance's formula unit. In the first option, the number of ions is 2 In the second option, the number of ions is 1. In the third option, the number of ions is 4. In fourth option, the number of ions is 3 
Hence, the correct option is option (C) .

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