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Q.

For 2SO2+O22SO3 , equilibrium pressures of SO3  & O2  are 0.4 atm & 0.2 atm respectively. If the total pressure is 1 atm, Kp for 2SO32SO2+O2 is

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a

0.04 atm

b

5 atm

c

0.2 atm

d

0.8 atm

answer is A.

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Detailed Solution

Given,PSO3=0.4atmPeq=PSO2+PSO3+PO2  PO2=0.2atmPSo2=10.6=0.4atm  

PSO2=?

                     2SO32SO2+O2

       Kp=(0.4)2(0.2)(0.4)2

              =0.4×0.4×0.20.4×0.4   

              =0.2atm       

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For 2SO2+O2⇌2SO3 , equilibrium pressures of SO3  & O2  are 0.4 atm & 0.2 atm respectively. If the total pressure is 1 atm, Kp for 2SO3⇌2SO2+O2 is