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Q.

For 3s orbital of hydrogen atom, the normalized wave function is ψ3S=1813π1a03/22718ra0+2r2a02er3a0 
If  distance between the radial nodes is d. Calculate the value of d1.73  a0

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answer is 3.

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Detailed Solution

ψ2=02718ra0+2r2a02=0 2r2-18a0r+27a02 =0 r=18a0±10.39a04 solving two values are obtained 3.76 and 1 distance between radial nodes (d) = 3.76-1=2.76 d1.730a0=2.761.73×0.53=3 

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