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Q.

For a Ag-Zn button cell, net reaction is 
Zn(s)+Ag2O(s)ZnO(s)+2Ag(s) ΔGf0Ag2O=11.21kJmol1 ΔGf0(ZnO)=318.3kJmol1  ThenEcell  ofthebuttoncellis 

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a

1.591V

b

–1.621 V

c

–1.591 V

d

3.182V

answer is C.

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Detailed Solution

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The equations taking palce in button cell are 

Anode:Zn +12O2ZnO+2e-   ;G=-318.3 kJ mol-1 Cathode Ag2O +2e-2Ag +12O2; G= + 11.21 kJmol-1 -------------------------------- The overall reaction:Zn +Ag2O ZnO+2Ag         n= 2  --------------------------------

Greactiono=G(ZnO)o-G(Ag2O)o                    =-318.3 +11.21                     =-307 kJ Go  =- nFEcello Ecello=-GonF=--307×1000 2×96500=+1.591V

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