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Q.

For a cell reaction involving two electron change, the standard EMF of the cell is 0.295 V at 250C. The equilibrium constant of the reaction at 250C will be

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a

29.5×102

b

10

c

1×1010

d

2.95×1010

answer is C.

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Detailed Solution

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According to Nernst equation,

E=E00.059nlogQ  at  250C

At equilibrium, E=0,Q=K

  0=E00.059nlogKE0=0.059nlogK

logK=E0×n0.059logK=0.295×20.059

K=anti  log0.295×20.059K=1×1010

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