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Q.

For a cell reaction, Cu2+(C1,aq)+Zn(s)Zn2+(C2,aq)+Cu(s), of an electro chemical cell, the change in standard free energy, ΔG0 at a given temperature is

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a

In C1

b

0.05912logC2C1

c

In C2

d

In (C1+C2)

answer is B.

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Detailed Solution

From given data 

Anodic reaction             ZnZn+2+2e

Cathodic reaction           Cu+2+2eCu

                                   ----------------------------------

                                    Zn+Cu+2Zn+2+Cu

According to Nernst euation

E  Cell=E0 Cell0.059n[Zn+2][Cu+2]

E  CellE0 Cell  gives  change  in Gibbs free energy of reaction since

ΔG0  and E0  related as  ΔG0=nFE0

So change in Gibbs free energy   =0.05912logC2C1

                                                                           n= no of electrons involved

                                                                                    F=Faraday (36500 C) of charge

                                                                                 2.303RTF=0.059V

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