Q.

For a chemical reaction, A ~ B, the rate of the reaction is 2×103moldm3s when the initial concentration is 0.25moldm3 The rate of the same reaction is 1.6×102moldm3s when the initial concentration is0.1  mol dm3.The order of the reaction is:

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a

2

b

1

c

0

d

3

answer is B.

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Detailed Solution

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We know that,rate = k [A]" where R is rate constant is order of reaction and [A] is concentration of reactant.

Given:Rate, =2×103moldm3s;A0=0.05moldm3

 Rate II =1.6×102moldm3s;A0=0.1moldm3 2×103=k[0.05]n(1);1.6×102=k[0.1]n

Dividing (1) by (2),we get; 2×1031.6×102=0.050.10n

or (0.05)n(0.05)n×2n or 12n=18 or 123. Hence, n=3

So,the correct answer is (b)

 

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