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Q.

For  a concentrated solution of a weak electrolyte (Keq = equilibrium constant ) A2B3 of concentration ‘c’, the degree of dissociation ‘α’ is 

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a

Keq5c415

b

Keq25c215

c

Keq6c515

d

Keq108c415

answer is B.

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Detailed Solution

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           A2B3 2A3++ 3B2

Initial    C

final CCα   2Cα    (3Cα)

From law of mass action

Keq=(2Cα)2×(3Cα)3(CCα)α<<11α1Keq=22×33×C5×α5(1α)×CKeq=108C4×α5α=Keq108C415

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