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Q.

For a dibasic acid, H2AHA-+H+(K1)
HA-A2-+H+(K2);
H2A2H +A2-(K) then,

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a

K = K2/K1

b

K = K1.K2

c

K = K1+ K2

d

K = K1/K2

answer is D.

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Detailed Solution

K1=[HA][H+][H2A]
For reaction 2;
K2=[A2-][H+][HA]
For reaction 3;
K=[A2-][H+]2[H2A]
On solving this further for K = K1.K2
K=K1.K2
   =  [HA][H+][H2A] X[A2-][H+][HA]
   =   [A2-][H+]2[H2A]
Hence, the correct answer is option (D)K = K1.K2.

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