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Q.

For a dilute solution containing 2.5 g of non-volatile non-electrolyte solute in 100 g of water, the elevation in boiling point at 1 atm pressure is 2°C. Assuming concentration of solute is much lower than the concentration of solvent, the vapour pressure (mm of Hg) of the solution is (take Kb = 0.76 kg mol–1)

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a

718

b

724

c

736

d

740

answer is A.

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Detailed Solution

ΔTb=KbwtGmt1000Mwt of solvent Gmt=9.5P0PP0=WmMW760P=36P=724

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