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Q.

For a dimerization reaction, 2A(g)A2(g), at 298 K, 

ΔU=20kJmol1,ΔS=30JK1mol1, then the - ΔGΘ will be ________ J. 

 

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answer is 13537.

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Detailed Solution

ΔH0=ΔU0+ΔnRT Δn=1ΔH0=200001×8.314×298=22477J/moleΔG0=ΔH0TΔS0ΔG0=22477J/ mole 298(30J/mole)=13537J

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