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Q.

For a diprotic acid, which of the following is true for 1^st and 2^nd ionisation constants (K_a1and K_a2)?

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a

$K_{a_{1}} > K_{a_{2}}$

b

$K_{a_{1}} = K_{a_{2}}$

c

$K_{a_{2}} > K_{a_{1}}$

d

$K_{a_{2}} \geq K_{a_{1}}$

answer is B.

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Detailed Solution

For a diprotic acid, further ionisation is difflcult, therefore

$K_{a_{1}} > K_{a_{2}}$

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