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Q.

For a first-order reaction A products

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a

a plot of reciprocal of concentration of the reactant versus time is a straight line.

b

the time taken for the completion of 75% reaction is thrice of half-life time

c

the pre-exponential factor in the Arrhenius equation has the dimension of time.

d

the degree of dissociation of reactant is equal to 1 - exp (- kt).

answer is A.

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Detailed Solution

For a first order reaction

ln[A][A]0=-kt    or [A][A]0=e-kt     i.e. [A]0(I-α)[A]0=e-kt                α=1-e-kt   i.e.

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