Q.

For a gaseous reaction : A(g) 3B(g) + C(g), ΔH is positive and the reaction attains equilibrium at

1 bar total pressure and 400K. Identify the incorrect statements regarding the above reaction.

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a

ΔG°=0 for the above reaction at equilibrium

b

On increase of temperature, equilibrium will be shifted in forward direction 

c

When inert gas is introduced into a rigid container containing above equilibria equilibrium

 shifts towards left         

d

If volume of vessel containing the above equilibria is increased without change in temperature

then partial pressure of B decreases as compared to original equilibrium partial pressure of B.

answer is B, C.

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Detailed Solution

A(g) 3B(g) + C(g); ΔH = + ve at 400 K

Ptotal at equilibrium = 1 bar

On increasing T, reaction moves in forward direction. 

 On introducing inert gas at constant T. total pressure increases but partial pressure remains the same so no effect at equilibrium.

at 400 K, KP 1 (since Ptotal = 1 bar)

ΔG400K0 =  RT ln KP ¹ 0

If V is increased, partial pressure of each species would be less than initital value.

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For a gaseous reaction : A(g) ⇌ 3B(g) + C(g), ΔH is positive and the reaction attains equilibrium at1 bar total pressure and 400K. Identify the incorrect statements regarding the above reaction.