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Q.

For a gaseous reaction, following data is given:

AB,k1=1015e2000/TCD,k2=1014e1000/T

The temperature at which k1=k2 is: 

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a

1000 K

b

868.82 K

c

2000 K

d

434.2 K

answer is D.

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Detailed Solution

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When k1=k2

1015e2000/T=1014e1000/T10=e1000/T2.303log10=1000TT=434.2K

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