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Q.

For a given reaction, the product of half life (t1/2) and the square of initial concentration of the reactant is constant. Then the order of reaction is

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a

zero

b

three

c

two

d

unity

answer is A.

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Detailed Solution

We know that half life is related to concentration as:

t12=[A]1n where n is the order of the reaction   Here n=2 t12=[A]12=1[A] For n=0, t12=[A]10=[A] If t12 is doubled, [A] is also doubled then the reaction is of zero order. 

 

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