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Q.

For a hydrogenic ion kinetic energy of electron in its 3rd excited state is found to be 54.4 eV. Then series limit 1λ for Balmer series, for this ion, is

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a

109678  ×  16  cm1

b

109678  /  16  cm1

c

109678  ×  4  cm1

d

109678  ×  64  cm1

answer is A.

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Detailed Solution

KE=13.6Z2n2eV/atom       54.4  =  13.6  ×  Z242       Z2=64for    Balmer   series1λ=RZ2  12212for   series    limit=109678  ×  64  141cm1=109678  ×16  cm1

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