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For a hypothetical gas containing molecules as point masses and having non-zero intermolecular attractions, which of the following is correct?

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Graph of $Z v / s \frac{1}{V}$ at a particular temperature will have negative slope

The gas shows positive deviations from ideal gas behavior

The gas will be difficult to compress as compared to ideal gas

2 moles of the gas at a temperature of 273 K can be stored in a 45 litre of container at 1 atm pressures

answer is B.

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Detailed Solution

$[P + \frac{a}{V_{m^{2}}}] V_{m} = R T \Rightarrow Z = 1 - \frac{a}{V_{m} R T}$

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