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Q.

For a parallel reaction,

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If k1 and k2 are rate constant of disappearance of A as per reaction I and reaction II and k1=103 sec1 and k2=2×103 sec1 [Assume initially only A is present then identify the option(s) which is (are) not correct.]

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a

After infinite time total moles will be between 2 to 3 if initially 1 mole of A is taken.

b

Ratio of moles of B to C will be 1 : 2 at any instant.

c

At some time concentration of A, B and C all will be same.

d

In 693 sec. around 18 of initial reactant taken would be left.

answer is A, D.

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Detailed Solution

(a) [B][C]=3k12k2=3×1034×103=34

(b) nA=1xy;nB=3x;nC=2y

At t;(x+y)1

nTotal =3x+2y=x+2 (lies between 2-3) 

(c) t1/2(A)=ln23×103 sec

No. of half-lives in 693 sec=6930.693×3×103

[A]t=[A]023

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